Printable Bioelectronics To Investigate Functional Biological Interfaces

Thin‐film transistors can be used as high‐performance bioelectronic devices to accomplish tasks such as sensing or controlling the release of biological species as well as transducing the electrical activity of cells or even organs, such as the brain. Organic, graphene, or zinc oxide are used as convenient printable semiconducting layers and can lead to high‐performance low‐cost bioelectronic sensing devices that are potentially very useful for point‐of‐care applications. Among others, electrolyte‐gated transistors are of interest as they can be operated as capacitance‐modulated devices, because of the high capacitance of their charge double layers. Specifically, it is the capacitance of the biolayer, being lowest in a series of capacitors, which controls the output current of the device. Such an occurrence allows for extremely high sensitivity towards very weak interactions. All the aspects governing these processes are reviewed here.     

Insights into the Catalytic Activity of Nitridated Fibrous Silica (KCC‐1) Nanocatalysts from 15N and 29Si NMR Spectroscopy Enhanced by Dynamic Nuclear Polarization

Fibrous nanosilica (KCC‐1) oxynitrides are promising solid‐base catalysts. Paradoxically, when their nitrogen content increases, their catalytic activity decreases. This counterintuitive observation is explained here for the first time using ¹⁵N‐solid‐state NMR spectroscopy enhanced by dynamic nuclear polarization.     

Micromotor‐Based Energy Generation

A micromotor‐based strategy for energy generation, utilizing the conversion of liquid‐phase hydrogen to usable hydrogen gas (H₂), is described. The new motion‐based H₂‐generation concept relies on the movement of Pt‐black/Ti Janus microparticle motors in a solution of sodium borohydride (NaBH₄) fuel. This is the first report of using NaBH₄ for powering micromotors. The autonomous motion of these catalytic micromotors, as well as their bubble generation, leads to enhanced mixing and transport of NaBH₄ towards the Pt‐black catalytic surface (compared to static microparticles or films), and hence to a substantially faster rate of H₂ production. The practical utility of these micromotors is illustrated by powering a hydrogen–oxygen fuel cell car by an on‐board motion‐based hydrogen and oxygen generation. The new micromotor approach paves the way for the development of efficient on‐site energy generation for powering external devices or meeting growing demands on the energy grid.     

Vortex-induced oscillations at low Reynolds numbers: Hysteresis and vortex-shedding modes

Results are presented for the numerical simulation of vortex-induced vibrations (VIVs) of a cylinder at low Reynolds numbers (Re). A stabilized space–time finite-element formulation is utilized to solve the incompressible flow equations in primitive variables. The cylinder, of low nondimensional mass (m^*=10), is free to vibrate in, both, the transverse and in-line directions. To investigate the effect of Re and reduced natural frequency, F_n, two sets of computations are carried out. In the first set of computations the Reynolds number is fixed (=100) and the reduced velocity (U^*=1/F_n) is varied. Hysteresis, in the response of the cylinder, is observed at the low- as well as high-end of the range of reduced velocity for synchronization/lock-in. In the second set of computations, the effect of Reynolds number (50Re500) is investigated for a fixed reduced velocity (U^*=4.92). The effect of the Reynolds number is found to be very significant for VIVs. While the vortex-shedding mode at low Re is 2S (two single vortices shed per cycle), at Re300 and larger, the P+S mode of vortex shedding (a single vortex and one pair of counter-rotating vortices are released in each cycle of shedding) is observed. This is the first time that the P+S mode has been observed for a cylinder undergoing free vibrations. This change of vortex-shedding mode is hysteretic in nature and results in a very large increase in the amplitude of in-line oscillations. Since the flow ceases to remain two-dimensional beyond Re200, it remains to be seen whether the P+S mode of shedding can actually be observed in reality for free vibrations.     

Wave propagation in an incompressible transversely isotropic fibre-reinforced elastic media

The boundary conditions at free surface of an incompressible, transversely isotropic elastic half-space are satisfied to obtain the reflection coefficients for the case when outer slowness section is re-entrant. Two quasi-shear waves will be reflected for an angular range of direction of incident wave. The numerical illustrations of reflection coefficients are presented graphically for three arbitrary materials.     

On the representation of the interaction energy between two polar molecules

Summary An attempt has been made to represent the interaction energy between two polar molecules by using an effective relative orientation of the pair of the colliding molecules. Calculations made for gaseous ammonia show fairly satisfactory results.